Effect of native bacteria Sinomonas flava 1C and Acidithiobacillus ferrooxidans on desulphurization of Meghalaya coal and its combustion properties

Abstract

Coal collected from Meghalaya state situated in northeastern (NE) region of India contains about 6.17% total sulphur (4.7% organic) with a gross calorific value of 26,208 J/g. In the present study, the coal sample was subjected to biodesulphurization along with optimization of various process parameters using a bacteria isolated from the native coal mine site. The native bacterium was identified to be Sinomonas flava 1C and reported first time for the capability to remove about 40% of sulphur from the coal. An innovative two-step sequential leaching using S. flava 1C followed by Acidithiobacillus ferrooxidans was used in the present study to enhance desulphurization. Sequential leaching resulted in 50-53% of sulphur removal from the coal sample. Sequential leaching reduced the sulphur content to 3.08% (organic 2.15% + pyritic 0.1% and 0.85% of sulphate sulphur) in -500+300 mu m size fraction of coal. Analytical characterization indicated that the energy value of coal was not affected adversely due to the biodesulphurization process rather its calorific value increased from 26,208 J/g to 29,481 J/g. (C) 2013 Elsevier Ltd. All rights reserved.