In this Investigation, the evolution and formation of graphitized microstructure of cast iron has been studied by using micro Raman spectroscopy and electron probe microanalysis (EPMA). The samples were prepared by carbothermic reduction of iron ore powder by plasma smelting in an extended arc thermal plasma reactor. Magnesium was added in the ladle to spherodize the graphite. Elemental mapping of the sample across the spherulites and flakes was performed by EPMA. Raman scattering data were collected at different positions across graphite spherulites and flakes. Micro Raman analysis shows graphite peaks at 1350 cm(-1) (D), 1580 cm(-1) (G), and higher order graphite peaks for both spherulites and flakes. Additional peaks between 200 and 800 cm(-1) are found to be present only in the case of spherulites. These extra peaks originate from cementite (Fe3C) present in and around the spherulites. It is inferred from the available experimental data that graphite spherulites are formed in areas richer in cementite.
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