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Effect of organic extractants on the electrocrystallization of nickel from aqueous sulphate solutions

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dc.contributor.author Tripathy, B.C.
dc.contributor.author Singh, P.
dc.contributor.author Muir, D.M.
dc.contributor.author Das, S.C.
dc.date.accessioned 2018-10-01T12:21:53Z
dc.date.available 2018-10-01T12:21:53Z
dc.date.issued 2001
dc.identifier.citation Journal Of Applied Electrochemistry, 31(3), 2001: 301-305
dc.identifier.issn 0021-891X
dc.identifier.uri http://ore.immt.res.in/handle/2018/962
dc.description.abstract The effect of the presence of commercial organic extractants LIX 84I, Cyanex 272, D2EHPA, Versatic 10 and TBP with or without Mg2+ on various electrodeposition parameters for nickel deposition on stainless steel cathode from aqueous sulphate solutions was investigated. The parameters included cathodic current efficiency, deposit morphology, crystal orientation and cathodic polarization. There was no significant variation in the current efficiency in the presence of these additives, but changes were observed in the deposit morphologies and crystal orientations even though all the deposits were bright, smooth and coherent. Changes were also observed in the cathodic polarization behaviour during nickel electrocrystallization in the presence of these additives. The effect of the additives on the electrokinetic parameter, exchange current density (i(0)) has also been investigated.
dc.language en
dc.publisher Kluwer Academic Publishers
dc.relation.isreferencedby SCI
dc.rights Copyright [2001]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.title Effect of organic extractants on the electrocrystallization of nickel from aqueous sulphate solutions
dc.type Journal Article
dc.affiliation.author Murdoch Univ, Dept Chem, Murdoch, WA 6150, Australia


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