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Catalytic activity of transition metal mixed amorphous aluminium phosphate towards alcohol conversion reactions.

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dc.contributor.author Mishra, T.
dc.contributor.author Parida, K.M.
dc.contributor.author Rao, S.B.
dc.contributor.editor Rao, T.S.R.
dc.contributor.editor Dhar, G.M.
dc.date.accessioned 2018-10-01T12:20:40Z
dc.date.available 2018-10-01T12:20:40Z
dc.date.issued 1998
dc.identifier.citation Recent Advances In Basic And Applied Aspects Of Industrial Catalysis, 113, 1998: 963-973
dc.identifier.isbn 0-444-82920-2
dc.identifier.issn 0167-2991
dc.identifier.uri http://ore.immt.res.in/handle/2018/723
dc.description.abstract The conversion(dehydration/dehydrogenation) of 2-propanol and methanol over M0.05Al0.95PO4 (M=V, Cr, Mn, Fe, Co, or Ni) catalysts were studied at different temperatures and flow rates in a fixed bed catalytic reactor. The activation and kinetic parameters were calculated using Arrhenius and frying equations. Among all the samples VOAlPO4 showed highest conversion and selectivity towards olefin formation. Selectivity studies indicated that 2-propanol and methanol dehydration followed a combination of parallel and consecutive pathways while surface poisoning studies suggested that mostly Bronsted acid sites participated in the dehydration as well as cracking reactions.
dc.language en
dc.publisher Elsevier
dc.relation.ispartofseries STUDIES IN SURFACE SCIENCE AND CATALYSIS
dc.relation.isbasedon 13th National Symposium and Silver Jubilee Symposium of Catalysis of India., Dehra Dun, India; APR 02-04, 1997
dc.relation.isreferencedby SCI
dc.rights Copyright [1998]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.subject Chemical Sciences
dc.subject Engineering
dc.title Catalytic activity of transition metal mixed amorphous aluminium phosphate towards alcohol conversion reactions.
dc.type Book Chapter
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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