dc.contributor.author |
Mishra, T. |
|
dc.contributor.author |
Parida, K.M. |
|
dc.contributor.author |
Rao, S.B. |
|
dc.contributor.editor |
Rao, T.S.R. |
|
dc.contributor.editor |
Dhar, G.M. |
|
dc.date.accessioned |
2018-10-01T12:20:40Z |
|
dc.date.available |
2018-10-01T12:20:40Z |
|
dc.date.issued |
1998 |
|
dc.identifier.citation |
Recent Advances In Basic And Applied Aspects Of Industrial Catalysis, 113, 1998: 963-973 |
|
dc.identifier.isbn |
0-444-82920-2 |
|
dc.identifier.issn |
0167-2991 |
|
dc.identifier.uri |
http://ore.immt.res.in/handle/2018/723 |
|
dc.description.abstract |
The conversion(dehydration/dehydrogenation) of 2-propanol and methanol over M0.05Al0.95PO4 (M=V, Cr, Mn, Fe, Co, or Ni) catalysts were studied at different temperatures and flow rates in a fixed bed catalytic reactor. The activation and kinetic parameters were calculated using Arrhenius and frying equations. Among all the samples VOAlPO4 showed highest conversion and selectivity towards olefin formation. Selectivity studies indicated that 2-propanol and methanol dehydration followed a combination of parallel and consecutive pathways while surface poisoning studies suggested that mostly Bronsted acid sites participated in the dehydration as well as cracking reactions. |
|
dc.language |
en |
|
dc.publisher |
Elsevier |
|
dc.relation.ispartofseries |
STUDIES IN SURFACE SCIENCE AND CATALYSIS |
|
dc.relation.isbasedon |
13th National Symposium and Silver Jubilee Symposium of Catalysis of India., Dehra Dun, India; APR 02-04, 1997 |
|
dc.relation.isreferencedby |
SCI |
|
dc.rights |
Copyright [1998]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
dc.subject |
Chemical Sciences |
|
dc.subject |
Chemical Sciences |
|
dc.subject |
Engineering |
|
dc.title |
Catalytic activity of transition metal mixed amorphous aluminium phosphate towards alcohol conversion reactions. |
|
dc.type |
Book Chapter |
|
dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|