| dc.contributor.author |
Das, N.N. |
|
| dc.contributor.author |
Das, R. |
|
| dc.date.accessioned |
2018-10-01T12:20:21Z |
|
| dc.date.available |
2018-10-01T12:20:21Z |
|
| dc.date.issued |
1997 |
|
| dc.identifier.citation |
Polyhedron, 16(12), 1997: 2135-2140 |
|
| dc.identifier.issn |
0277-5387 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/644 |
|
| dc.description.abstract |
Two mixed metal binuclear complexes, [(NH3)(5)Co-III (nta)Cu-II](2+) (1) and [(NH3)(5)Co-III(pyc)Cu-II](4+) (2; nta = nitrilotriacetate and pyc = pyridine-2-carboxylate) have been synthesized and characterized on the basis of elemental analysis; UV-vis, IR, ESR spectroscopy; magnetic and electrochemical measurements. A stopped flow kinetic study indicated that the dissociation of (NH3)(5)Co(nta)Cu2+ occured via spontaneous and acid catalysed paths. (C) 1997 Elsevier Science Ltd. |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [1997]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Chemical Sciences |
|
| dc.subject |
Chemical Sciences |
|
| dc.title |
Synthesis, characterization and dissociation of mixed valent binuclear complexes |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|