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STUDIES ON INITIAL DISSOLUTION KINETICS FROM POLARIZATION DATA .5. SPHALERITE IN FERRIC-CHLORIDE

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dc.contributor.author Paramguru, R.K.
dc.date.accessioned 2018-10-01T12:19:53Z
dc.date.available 2018-10-01T12:19:53Z
dc.date.issued 1995
dc.identifier.citation Transactions Of The Indian Institute Of Metals, 48(4), 1995: 295-300
dc.identifier.issn 0019-493X
dc.identifier.uri http://ore.immt.res.in/handle/2018/514
dc.description.abstract Electrochemical aspects of sphalerite dissolution in acidic ferric chloride have been investigated through concurrent polarization studies of individual half cell reactions. Mixed potential, E(m) and mixed current, i(m) obtained from intersections of such curves at different solution conditions have been analyzed to understand the initial dissolution kinetics. At lower ferric concentrations the overall process is found to be controlled by the cathodic diffusion process. The process control shifts to cathodic activation and then to anodic activation at higher concentration levels as ferric ion concentration increases. Activation energy values obtained support this conclusion.
dc.language en
dc.publisher Indian Institute Of Metals
dc.relation.isreferencedby SCI
dc.rights Copyright [1995]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Materials Sciences
dc.subject Materials Sciences
dc.title STUDIES ON INITIAL DISSOLUTION KINETICS FROM POLARIZATION DATA .5. SPHALERITE IN FERRIC-CHLORIDE
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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