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BEHAVIOR OF NI(II) IN THE H2O-NH3-SO2-MNO2 SYSTEM

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dc.contributor.author Das, P.K.
dc.contributor.author Anand, S.
dc.contributor.author Das, R.P.
dc.date.accessioned 2018-10-01T12:19:50Z
dc.date.available 2018-10-01T12:19:50Z
dc.date.issued 1995
dc.identifier.citation International Journal Of Mineral Processing, 43(1-2), 1995: 99-111
dc.identifier.issn 0301-7516
dc.identifier.uri http://ore.immt.res.in/handle/2018/496
dc.description.abstract Nickel losses have been observed from leach liquors obtained during extraction of metal values from ocean nodules using ammonium sulphite. Studies have been carried out to establish the reasons for such losses. Behaviour of Ni(II) in the following systems was studied: (a) NH3(NH4)(2)SO3- (b) NH3-partially oxidised (NH4)(2)SO3 using oxygen-H2O, and (c) NH3-partially oxidised (NH4)(2)SO3 using MnO3-H2O. Nickel added during or after reduction of MnO2 in NH3-(NH4)(2)SO3 solution resulted in its precipitation as a crystalline compound. The XRD pattern showed discrete peaks but did not correspond to any compound cited in ASTM. Detailed work of DT-TGA and chemical analysis supported the formation of Ni0.75Mn0.25(NH3)(4)S2O6 . 2 H2O in nodule leach liquor.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [1995]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Engineering
dc.subject Geosciences
dc.subject Geosciences
dc.subject Geosciences
dc.title BEHAVIOR OF NI(II) IN THE H2O-NH3-SO2-MNO2 SYSTEM
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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