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EXTRACTIVE SPECTROPHOTOMETRIC DETERMINATION OF COBALT USING CYANEX-272

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dc.contributor.author Reddy, B.R.
dc.contributor.author Sarma, P.V.R.B.
dc.date.accessioned 2018-10-01T12:19:41Z
dc.date.available 2018-10-01T12:19:41Z
dc.date.issued 1994
dc.identifier.citation Talanta, 41(8), 1994: 1335-1339
dc.identifier.issn 0039-9140
dc.identifier.uri http://ore.immt.res.in/handle/2018/446
dc.description.abstract Cyanex-272 forms a blue-colored complex with Co(II) in the organic phase. The complex shows three absorption maxima. The peak at 635 nm has been used for developing a spectrophotometric procedure for cobalt determination. Beer's law was found to be obeyed in the range 0.295-2.36 mg of cobalt. The nature of the extracted species was found to be CoR2.HR. The molar absorptivity was found to be 3.07 x 10(2)l. mol-1. cm-1 at 635 nm. The method was applied for cobalt determination in solutions obtained from Beta Cake and a super alloy and was found to give values close to the actual ones. Easy regeneration of the reagent (Cyanex-272) for re-use is the main advantage of the present method.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [1994]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.title EXTRACTIVE SPECTROPHOTOMETRIC DETERMINATION OF COBALT USING CYANEX-272
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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