Crafting 3D Hierarchical NiO@MXene Derived TiO2/Graphene Heterostructured Electrode for Ultrasensitive Paraquat and Heavy Metal Detection

Abstract

The fabrication of electrochemical sensing electrode with high sensitivity is vital for environmental monitoring of toxic contaminants in water and food sources. Here, a 3D hierarchical NiO@MXene derived TiO2/graphene (NMG) heterostructured electrode is developed using laser writing technique. The NMG heterostructured electrode is employed for voltammetric detection of both pesticide and heavy metals. For pesticide detection, NMG is employed to monitor paraquat (PQ) in 0.1 m phosphate buffer using stripping voltammetry, achieving a remarkable limit of detection of 0.0092 mu m under optimized conditions. Its practical applicability is demonstrated by successfully detecting PQ in real samples of aqueous coriander leaf extract. Interestingly, NMG exhibits high selectivity, repeatability, and reproducibility, highlighting its potential as a robust electrode for PQ detection. Furthermore, NMG facilitates individual and simultaneous detection of heavy metals, including Cd2+, Pb2+, Cu2+, and Hg2+ with detection limits as 0.0036, 0.0018, 0.0043, and 0.0027 mu m, respectively, in the 0.1-2 mu m range using 0.1 m acetate buffer solution. The synergistic material combination with their complimentary physicochemical properties of NMG significantly enhance the electrochemical performance, making NMG as an effective electrode for sensitive and selective detection of PQ and heavy metals.