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Inducing piezoelectric behavior in a copper iodide cubane cluster-based metal-organic framework via linker engineering

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dc.contributor.author Panda, SN
dc.contributor.author Pradhan, P
dc.contributor.author Nath, S
dc.contributor.author Mohapatra, J
dc.contributor.author Patra, BK
dc.contributor.author Biswal, BP
dc.date.accessioned 2025-07-22T08:55:21Z
dc.date.available 2025-07-22T08:55:21Z
dc.date.issued 2025
dc.identifier.citation Chemical Communications, 61, 2025; 2536-2539
dc.identifier.issn 1359-7345
dc.identifier.uri http://ore.immt.res.in/handle/2018/3654
dc.description DST-INSPIRE Faculty Grant [IFA19-MS161]; SERB-Start-up research grant, Govt. of India [SRG/2022/000162]; Max Plank Society; DAE, Govt. of India; NISER Bhubaneswar, Odisha; SERB [GAP-341]; [CSPS24/RDSF/IHP-000008]
dc.description.abstract Cu4I4 cubane-type secondary building units are reticulated with a piperazine linker at room temperature to crystallize the metal-organic frameworks (MOFs) Cu4I4(Pip)2 in a non-centrosymmetric P6222 space group. For the first time, cubane cluster type MOF's strong piezoelectric nature has been studied by switching spectroscopy piezo force microscopy (SS-PFM) and piezo force microscopy (PFM) mapping of the crystal, with piezoelectric constant (d33) similar to 52.33 pm V-1, highlighting its potential for mechanical energy harvesting processes.
dc.language en
dc.publisher Royal Soc Chemistry
dc.relation.isreferencedby SCI
dc.rights Copyright [2025]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.title Inducing piezoelectric behavior in a copper iodide cubane cluster-based metal-organic framework via linker engineering
dc.type Journal Article
dc.affiliation.author Natl Inst Sci Educ & Res Bhubaneswar, Sch Chem Sci, Khurja 752050, Odisha, India


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