| dc.contributor.author |
Prasad, T.P. |
|
| dc.contributor.author |
Kanungo, S.B. |
|
| dc.contributor.author |
Ray, H.S. |
|
| dc.date.accessioned |
2018-10-01T12:19:25Z |
|
| dc.date.available |
2018-10-01T12:19:25Z |
|
| dc.date.issued |
1992 |
|
| dc.identifier.citation |
Thermochimica Acta, 203, 1992: 503-514 |
|
| dc.identifier.issn |
0040-6031 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/352 |
|
| dc.description.abstract |
An account of non-isothermal kinetics, with respect to origin, usefulness, limitations, successes and failures compared with isothermal kinetics as applied to solid state heterogeneous reactions, is presented and discussed. The so-called non-relevance of non-isothermal kinetics to such reactions is traced to the over-simplication of mathematical expressions and experimental factors rather than to the non-applicability of the Arrhenius equation itself to non-isothermal heterogeneous kinetics. The usefulness of the variation in A with variation in E as a function of experimental factors, as manifested in the kinetic compensation effect, is indicated to predict the effect of experimental parameters on kinetics. |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [1992]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Physical Sciences |
|
| dc.subject |
Chemical Sciences |
|
| dc.subject |
Chemical Sciences |
|
| dc.title |
NONISOTHERMAL KINETICS - SOME MERITS AND LIMITATIONS |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|