| dc.contributor.author |
Kamali, K |
|
| dc.contributor.author |
Narayana, C |
|
| dc.date.accessioned |
2023-10-04T12:48:38Z |
|
| dc.date.available |
2023-10-04T12:48:38Z |
|
| dc.date.issued |
2022 |
|
| dc.identifier.citation |
Materials Today-Proceedings, 49, 2022; 1196-1199 |
|
| dc.identifier.issn |
2214-7853 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/3269 |
|
| dc.description |
Department of Science and Technology for the National Post Doctoral Fellowship [PDF/2016/001193] |
|
| dc.description.abstract |
Pressure-dependent structural and chemical changes of the metal-organic framework (MOF) compound MIL-47(V) have been investigated up to 2.9 GPa using pore-penetrating liquid, water as pressure transmitting medium (PTM). Under compression, MIL-47(V) undergoes reversible replacement of the free terephthallic acid (TPA) by H2O molecules near 0.7 and 1.5 GPa. The observed structural and chemical changes observed in hydroxyl linked vanadium octahedra in as-synthesised MIL-47(V) demonstrate unique high pressure chemistry depending on the type of bridging octahedral group in framework structure. The tunable bridging group in MIL-47(V) allows postsynthetic room temperature by pressureinduced removal and insertion of organic molecules in MOFs through the formation of stable phases at ambient conditions. (C) 2021 Elsevier Ltd. All rights reserved. |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isbasedon |
Global Conference on Recent Advances in Sustainable Materials (GC-RASM), Mangalore, India; JUL 29-30, 2021 |
|
| dc.relation.isreferencedby |
NON-SCI |
|
| dc.rights |
Copyright [2022]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Materials Science |
|
| dc.title |
Pressure dependent chemical changes of adsorbed water in MIL-47 (V) by raman spectroscopy |
|
| dc.type |
Proceedings Paper |
|
| dc.affiliation.author |
JNCASR, Bangalore 560064, Karnataka, India |
|