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The Journey from Porous Materials to Metal-organic Frameworks and their Catalytic Applications: A Review

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dc.contributor.author Panda, J.
dc.contributor.author Sahoo, T.
dc.contributor.author Swain, J.
dc.contributor.author Panda, P.K.
dc.contributor.author Tripathy, B.C.
dc.contributor.author Samantaray, R.
dc.contributor.author Sahu, R.
dc.date.accessioned 2023-07-28T05:01:30Z
dc.date.available 2023-07-28T05:01:30Z
dc.date.issued 2023
dc.identifier.citation Current Organic Synthesis, 20(2), 2023: 220-237
dc.identifier.issn 1570-1794
dc.identifier.uri http://ore.immt.res.in/handle/2018/3160
dc.description.abstract Metal-Organic Frameworks (MOFs), a class of inorganic-organic hybrid materials, have been at the center of material science for the past three decades. They are synthesized by metal ions and organic linker precursors and have become very potential materials for different applications ranging from sensing, separation, catalytic behaviour to biomedical applications and drug delivery, owing to their structural flexibility, porosity and functionality. They are also very promising in heterogeneous catalysis for various industrial applications. These catalysts can be easily synthesized with extremely high surface areas, tunable pore sizes, and incorporation of catalytic centers via post-synthetic modification (PSM) or exchange of their components as compared to traditional heterogeneous catalysts, which is the preliminary requirement of a better catalyst. Here, in this review, we have presented the history of MOFs, different synthesis procedures, and MOF-catalysed reactions; for instance, coupling reactions, condensation reactions, Friedel-Crafts reaction, oxidation, etc. Special attention has been given to MOFs containing different catalytic centers, including open metal sites, incorporation of catalytic centers through PSM, and bifunctional acid-base sites. The important role of catalytic centers present in MOFs and reaction mechanisms have also been outlined with examples.
dc.language en
dc.publisher Bentham Science
dc.relation.isreferencedby SCI
dc.rights Copyright [2023]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.title The Journey from Porous Materials to Metal-organic Frameworks and their Catalytic Applications: A Review
dc.type Journal Article
dc.affiliation.author KIIT, Bhubaneswar 751024, Odisha, India


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