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Molecular modeling studies of oleate adsorption on iron oxides

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dc.contributor.author Rath, S.S.
dc.contributor.author Sinha, N.
dc.contributor.author Sahoo, H.
dc.contributor.author Das, B.
dc.contributor.author Mishra, B.K.
dc.date.accessioned 2018-10-01T12:25:27Z
dc.date.available 2018-10-01T12:25:27Z
dc.date.issued 2014
dc.identifier.citation Applied Surface Science, 295, 2014: 115-122
dc.identifier.issn 0169-4332
dc.identifier.uri http://ore.immt.res.in/handle/2018/1969
dc.description.abstract Comparative studies of oleate interaction with hematite, magnetite and goethite using density functional calculations are presented. The approach is illustrated by carrying out geometric optimization of oleate on the stable and most exposed planes of hematite, magnetite, and goethite. Interaction energies for oleate-mineral surface have been determined, based on which, magnetite is found to be forming the most stable complex with oleate. Trend as obtained from the quantum chemical calculations has been validated by contact angle measurements and flotation studies on hematite, magnetite and goethite with sodium oleate at different pH and collector concentrations. (C) 2014 Elsevier B. V. All rights reserved.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [2014]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.subject Materials Sciences
dc.subject Physical Sciences
dc.subject Physical Sciences
dc.title Molecular modeling studies of oleate adsorption on iron oxides
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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