| dc.contributor.author |
Pal, A. |
|
| dc.contributor.author |
Bag, B. |
|
| dc.date.accessioned |
2018-10-01T12:24:56Z |
|
| dc.date.available |
2018-10-01T12:24:56Z |
|
| dc.date.issued |
2012 |
|
| dc.identifier.citation |
Journal Of Photochemistry And Photobiology A-Chemistry, 240, 2012: 42-49 |
|
| dc.identifier.issn |
1010-6030 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/1724 |
|
| dc.description |
DST, New Delhi [SR/FTP/CS-138/2006] |
|
| dc.description.abstract |
The rhodamine based chemosensor 1 exhibited highly selective and sensitive detection of Hg(II) ion in MeCN-H2O mixture observable through amplified absorption and emission signals with a colour change from colourless to pink. Its thiophenyl subunit plays a predominant role in observed allosteric cooperativity in binding of both the Hg(II) ions of its 1:2 (L:M) complex stoichiometry. The anion induced 'turn-off' signalling responses of the Hg(II)-complex of 1 and subsequent 'turn-on' responses with further addition of Hg(II) here demonstrated its repetitive usability as a probe for Hg(II) ion detection. (C) 2012 Elsevier B.V. All rights reserved. |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [2012]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Chemical Sciences |
|
| dc.title |
Hg(II) ion specific dual mode signalling in a thiophene derivatized rhodamine based probe and their complexation cooperativity |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|