| dc.contributor.author |
Mallick, S. |
|
| dc.contributor.author |
Rana, S. |
|
| dc.contributor.author |
Parida, K. |
|
| dc.date.accessioned |
2018-10-01T12:24:52Z |
|
| dc.date.available |
2018-10-01T12:24:52Z |
|
| dc.date.issued |
2012 |
|
| dc.identifier.citation |
Industrial & Engineering Chemistry Research, 51(23), 2012: 7859-7866 |
|
| dc.identifier.issn |
0888-5885 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/1673 |
|
| dc.description |
CSIR |
|
| dc.description.abstract |
A series of phosphomolybdic acid (5-20 wt % PMA) promoted zirconia-ceria (ZrO2-CeO2) mixed oxides were synthesized by an impregnation method and characterized by XRD, nitrogen adsorption/desorption, UV-vis DR spectroscopy, TPR/TPD, and P-31 MAS NMR spectroscopy. NMR spectra revealed that the catalyst retained the Keggin structure of PMA even after calcination at 500 degrees C. The catalysts were screened for the solvent-free liquid-phase oxidation of benzyl alcohols using hydrogen peroxide as the oxidizing agent. The sample of 15 wt % PMA/ZrO2-CeO2 showed 85% conversion and 96% selectivity to the corresponding aldehydes. |
|
| dc.language |
en |
|
| dc.publisher |
American Chemical Society |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [2012]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Engineering |
|
| dc.title |
Facile Method for the Synthesis of Phosphomolybdic Acid Supported on Zirconia-Ceria Mixed Oxide and Its Catalytic Evaluation in the Solvent-Free Oxidation of Benzyl Alcohol |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|