| dc.contributor.author |
Rana, A. |
|
| dc.contributor.author |
Bera, M. |
|
| dc.contributor.author |
Chowdhuri, D.S. |
|
| dc.contributor.author |
Bag, B. |
|
| dc.contributor.author |
Butcher, R.J. |
|
| dc.contributor.author |
Dalai, S. |
|
| dc.date.accessioned |
2018-10-01T12:23:50Z |
|
| dc.date.available |
2018-10-01T12:23:50Z |
|
| dc.date.issued |
2011 |
|
| dc.identifier.citation |
Journal Of Molecular Structure, 990(1-3), 2011: 102-109 |
|
| dc.identifier.issn |
0022-2860 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/1581 |
|
| dc.description |
DST, New Delhi [SR/FTP/CS-26/2007]; CSIR |
|
| dc.description.abstract |
One pot synthesis of a purely inorganic framework of azido-lead(II) complex with molecular formula [Pb-3(N-3)(6)](n) has been made by using 5-aminotetrazole (5-ATZ) ligand as starting material. X-ray single crystal structure determination revealed the presence of two types of Pb-centers (Pb1 and Pb2). One-dimensional propagation of Pb1 centers with azide segment gives an infinite zig-zag 1D chain along c-axis. 2D sheet is formed along bc- and ac-plane with the 1D chain. It is interesting to identify another infinite 1D chain along a-axis by connecting Pb2 centers via azide linkage. The compound displays an overall 3D structure. All the connectivity of azide in complex 1 show exclusive end-to-end (i.e., mu-1,3) binding. (C) 2011 Elsevier B.V. All rights reserved. |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [2011]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Chemical Sciences |
|
| dc.title |
3D purely inorganic lead-azide coordination polymer constructed by exclusive end-to-end azido binding |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
Vidyasagar Univ, Dept Chem & Chem Technol, Midnapore 721102, WB, India |
|