| dc.contributor.author |
Parida, K.M. |
|
| dc.contributor.author |
Sahoo, M. |
|
| dc.contributor.author |
Singha, S. |
|
| dc.date.accessioned |
2018-10-01T12:23:32Z |
|
| dc.date.available |
2018-10-01T12:23:32Z |
|
| dc.date.issued |
2010 |
|
| dc.identifier.citation |
Journal Of Molecular Catalysis A-Chemical, 329(1-2), 2010: 7-12 |
|
| dc.identifier.issn |
1381-1169 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/1517 |
|
| dc.description.abstract |
The paper reports the synthesis, characterization and catalytic evaluation of a Fe(III)-Schiff base complex intercalated Zn-Al layer double hydroxide (LDH). The immobilized complex was characterized by powder X-ray diffraction, FT-IR. UV-vis spectroscopy, N-2 adsorption desorption, scanning electron microscopy and TGA techniques. The immobilization complex was found to be an effective catalyst for oxidation of cyclohexane using H2O2 as an oxidant under mild conditions. A conversion of 45.5% of cyclohexane was obtained with selectivity of 100% of the cyclohexanone/cyclohexanol at 70 degrees C in 8 h in acetonitrile solvent. Recycling test of the catalyst showed that it was recovered and reused up to 3 more cycles without loss of performance. (C) 2010 Elsevier B.V. All rights reserved. |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [2010]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Chemical Sciences |
|
| dc.title |
Synthesis and characterization of a Fe(III)-Schiff base complex in a Zn-Al LDH host for cyclohexane oxidation |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|