| dc.contributor.author |
Parida, K.M. |
|
| dc.contributor.author |
Sahoo, M. |
|
| dc.contributor.author |
Singha, S. |
|
| dc.date.accessioned |
2018-10-01T12:23:21Z |
|
| dc.date.available |
2018-10-01T12:23:21Z |
|
| dc.date.issued |
2010 |
|
| dc.identifier.citation |
Journal Of Catalysis, 276(1), 2010: 161-169 |
|
| dc.identifier.issn |
0021-9517 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/1477 |
|
| dc.description.abstract |
A novel heterogeneous catalyst has been developed by immobilizing Ti(IV)-Schiff base complex in Zn-Al/LDH by an ion-exchange method Powder X-ray diffraction Fourier transform infrared spectroscopy diffuse reflectance UV-Visible spectroscopy N-2-adsorption and thermal studies confirm the successful intercalation of the Ti-complex within the LDH structure The supported catalyst shows an excellent catalytic activity in cyclohexene epoxidation reaction In this paper we report an environmentally benign reaction pathway in a solvent-free condition taking H2O2 as oxidant As high as 95% conversion of cyclohexene took place at 70 degrees C in 6 h The heterogeneous catalyst can be recovered easily and reused multiple times without significant loss in catalytic activity and selectivity which is a better green alternative for practical applications (C) 2010 Elsevier Inc All rights reserved |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [2010]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Chemical Sciences |
|
| dc.subject |
Engineering |
|
| dc.title |
A novel approach towards solvent-free epoxidation of cyclohexene by Ti(IV)-Schiff base complex-intercalated LDH using H2O2 as oxidant |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|