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Photocatalytic reduction of hexavalent chromium in aqueous solution over titania pillared zirconium phosphate and titanium phosphate under solar radiation

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dc.contributor.author Das, D.P.
dc.contributor.author Parida, K.
dc.contributor.author De, B.R.
dc.date.accessioned 2018-10-01T12:22:29Z
dc.date.available 2018-10-01T12:22:29Z
dc.date.issued 2006
dc.identifier.citation Journal Of Molecular Catalysis A-Chemical, 245(1-2), 2006: 217-224
dc.identifier.issn 1381-1169
dc.identifier.uri http://ore.immt.res.in/handle/2018/1228
dc.description.abstract The photo-reduction of hexavalent chromium was carried out varying different parameters such as pH, titania loading on zirconium phosphate (ZrP) and titanium phosphate (TiP), initial substrate concentration, irradiation time and catalyst dose. The reduction rate of chromium was favorable under acidic pH than in the alkaline pH. The dissolved oxygen imparts the minimum effect on the reduction of Cr(VI) as oxygen competes with the hexavalent chromium for the electron in the acidic solutions. Hexavalent chromium was completely reduced over titania pillared ZrP and TiP under solar radiation. This process of photo-reduction follows approximately pseudo first-order kinetics. (c) 2005 Elsevier B.V. All rights reserved.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [2006]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.title Photocatalytic reduction of hexavalent chromium in aqueous solution over titania pillared zirconium phosphate and titanium phosphate under solar radiation
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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