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Synthesis, characterization, and catalytic activity of phosphomolybdic acid supported on hydrous zirconia

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dc.contributor.author Mallik, S.
dc.contributor.author Dash, S.S.
dc.contributor.author Parida, K.M.
dc.contributor.author Mohapatra, B.K.
dc.date.accessioned 2018-10-01T12:22:24Z
dc.date.available 2018-10-01T12:22:24Z
dc.date.issued 2006
dc.identifier.citation Journal Of Colloid And Interface Science, 300(1), 2006: 237-243
dc.identifier.issn 0021-9797
dc.identifier.uri http://ore.immt.res.in/handle/2018/1200
dc.description.abstract A series of ecofriendly solid acid catalyst was synthesized by phosphomolybdic acid impregnated on hydrous zirconia (ZPMA) by an incipient wetness impregnation technique. The support and the resulting catalysts were characterized by X-ray diffraction, FTIR, EPNIA, BET surface area, acid sites. etc. These studies indicate that the phosphomolybdic acid keeps its Keggin-type structure unaltered up to 500 degrees C. Catalytic activities of the material were evaluated for the esterification of acetic acid reaction. The 12 wt% of phosphomolybdic acid supported on hydrous zirconia shows highest surface area, acid sites and gives about 86% conversion with 100% selectivity of n-butyl acetate. (c) 2006 Elsevier Inc. All rights reserved.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [2006]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Chemical Sciences
dc.title Synthesis, characterization, and catalytic activity of phosphomolybdic acid supported on hydrous zirconia
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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