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Separation of copper and zinc by supported liquid membrane using TOPS-99 as mobile carrier

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dc.contributor.author Sarangi, K.
dc.contributor.author Das, R.P.
dc.date.accessioned 2018-10-01T12:22:10Z
dc.date.available 2018-10-01T12:22:10Z
dc.date.issued 2004
dc.identifier.citation Hydrometallurgy, 71(3-4), 2004: 335-342
dc.identifier.issn 0304-386X
dc.identifier.uri http://ore.immt.res.in/handle/2018/1102
dc.description.abstract The separation of copper and zinc from an aqueous sulphate media by supported liquid membrane (SLM) using di-2-ethyl hexyl phosphoric acid (TOPS-99) as mobile carrier has been studied. Celgard-2500, a microporous polypropylene film, was used as the solid support for the liquid membrane. A plate and frame type of cell was used for the experiment. The effects of different parameters such as flow rate, pH of feed solution, TOPS-99 concentration in the membrane phase and acid concentration in strip solution on separation of copper and zinc were studied. It was observed that flow rate of 100 mL/min (velocity 85.7 m/h) was sufficient to reduce the resistances due to the aqueous boundary layer. Zinc was permeated in a pH region 1.5-5.0, while copper permeation started at pH 3.0. At pH 2.5, the co-permeation of copper with zinc was negligible, and a high separation factor was achieved at this pH. (C) 2004 Elsevier B.V. All rights reserved.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [2004]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Materials Sciences
dc.subject Materials Sciences
dc.title Separation of copper and zinc by supported liquid membrane using TOPS-99 as mobile carrier
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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