| dc.contributor.author |
Mallavadhani, U.V. |
|
| dc.contributor.author |
Mahapatra, A. |
|
| dc.contributor.author |
Narasimhan, K. |
|
| dc.contributor.author |
Sahoo, L.D. |
|
| dc.date.accessioned |
2018-10-01T12:21:59Z |
|
| dc.date.available |
2018-10-01T12:21:59Z |
|
| dc.date.issued |
2002 |
|
| dc.identifier.citation |
Indian Journal Of Chemistry Section B-Organic Chemistry Including Medicinal Chemistry, 41(7), 2002: 1460-1466 |
|
| dc.identifier.issn |
0376-4699 |
|
| dc.identifier.uri |
http://ore.immt.res.in/handle/2018/1019 |
|
| dc.description.abstract |
The O-alkylation (allylation/propargylation) of 3,5-dibromo-4-hydroxybenzaidehyde 1 and the corresponding acetophenone 2 results in the formation of aryl-aryl coupled product by loss of formyl groups, aryl-aryl ether and aryloxy acetone in addition to the expected O-allyl / propargyl ethers. While the thermal Claisen rearrangement of allyl ethers 1 and 2 furnishes the C-allyl products by loss of bromine, the propargyl ether 7 surprisingly resisted rearrangement and underwent oxidation to yield the corresponding carboxylic acid. |
|
| dc.language |
en |
|
| dc.publisher |
National Institute Of Science Communication And Information Resources - NISCAIR |
|
| dc.relation.isreferencedby |
SCI |
|
| dc.rights |
Copyright [2002]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository. |
|
| dc.subject |
Chemical Sciences |
|
| dc.title |
Interesting product formation during O-alkylation and subsequent rearrangement of two building blocks of dibromotyrosine based natural products |
|
| dc.type |
Journal Article |
|
| dc.affiliation.author |
CSIR-IMMT, Bhubaneswar 751013, Odisha, India |
|