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Liquid-liquid extraction of nickel at macro-level concentration from sulphate/chloride solutions using phosphoric acid based extractants

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dc.contributor.author Sarma, P.V.R.B.
dc.contributor.author Reddy, B.R.
dc.date.accessioned 2018-10-01T12:21:57Z
dc.date.available 2018-10-01T12:21:57Z
dc.date.issued 2002
dc.identifier.citation Minerals Engineering, 15(6), 2002: 461-464
dc.identifier.issn 0892-6875
dc.identifier.uri http://ore.immt.res.in/handle/2018/1001
dc.description.abstract Extraction of nickel was studied at macro-level concentrations (similar to0.5 M) from solutions containing sodium sulphate/chloride using the extractants D2EHPA, PC 88A and Cyanex 272. Increase of sodium salt concentration in the feed solution (0-1.0 M) resulted in decrease in nickel extraction. This influence is more prominent with the extractant D2EHPA. At a given nickel: sodium salt ratio, variation in nickel/sodium salt concentration influenced the extraction. Temperature (in the range of 30-45degreesC) and contact time (beyond one minute) had no effect on extraction. The loading capacity of 1.0 M D2EHPA, PC88A and Cyanex 272 (70% neutralised) was observed to be 17.7, 18.2, and 18.7 kg/m(3) in the sulphate system and 20.74, 20.75, and 20.35 kg/m(3) in the chloride system. The extracted species appears to be NiR2. (C) 2002 Elsevier Science Ltd. All rights reserved.
dc.language en
dc.publisher Elsevier
dc.relation.isreferencedby SCI
dc.rights Copyright [2002]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subject Engineering
dc.subject Geosciences
dc.subject Geosciences
dc.subject Geosciences
dc.title Liquid-liquid extraction of nickel at macro-level concentration from sulphate/chloride solutions using phosphoric acid based extractants
dc.type Journal Article
dc.affiliation.author CSIR-IMMT, Bhubaneswar 751013, Odisha, India


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